Pdf a study of the dehydration process of natural gas in. Water or other impurities present in the natural gas can increase the risk of damage to the pipeline as the result of corrosion or hydrate formation. The combination of 2 to 3 beds, a heater, a condenser, and a dust filter work together to dry natural gas to a point that will prevent harm to critical gas processing components that are downstream of the unit. A study of the dehydration process of natural gas in iraqi north gas company and the treatment methods of molecular sieve problems supervised by. A molecular sieve dehydration unit is actually a collection of components that support the saturation and regeneration of the material in order to remove water from the natural gas stream.
However, the typical glycol dehydration process is suitable for meeting pipeline gas specification as low as. Most commercial molecular sieve products used in process applications are in the form of shaped particles e. Taking the example of natural gas drying with molecular sieves, the dehydration unit is typically designed by the molecular sieve manufacturer. Mol sieve dehydration units provide an effective means to remove water vapor from a natural gas stream. Herold, contributing writer, amsterdam, the netherlands. Sorbead india profile molecular sieve suppliers in india. Molecular desiccant in natural gas dehydration process. As such, the title capex and opex considerations for gas dehydration technologies can be interpreted in several ways. Molecular sieve acts as an effective absorbent for gases and liquids. Molecular sieve dehydration processes, which are usually chosen for deep dehydration to meet a low water dew point for ngl recovery or lng production, will be discussed in. Natural gas dehydration by molecular sieves youtube. It is possible with molecular sieve dehydration units to get the water content of the gas stream. Natural gas dehydration by molecular sieves is one of the most promising processes.
Tegi t i b ti tteg is most common in absorption systems meg is most common in glycol injection systems. However, selecting the best adsorbents is only the. Natural gas dehydration 5 temperatures and the absorbed water is boiled out from teg during regeneration in a reboiler at high temperatures. Some physical properties of pure teg are given in the following text. Failure analysis and faults diagnosis of molecular sieve in natural gas dehydration. Lng dehydrationdrying of natural gas absorption and refrigeration with hydrate inhibition is the most common dehydration process used to meet pipeline sales specifications. Natural water of hydration is removed from this network by heating to produce uniform cavities which selectively adsorb molecules of a specific size. Twotower vs threetower system the petroskills may 2015 2 and october 2015 tip of the month totm 3 discussed the efficient operation of molecular sieve dehydration units. Glycol dehydration process an overview sciencedirect. To this day, uop remains a leading supplier of dehydration adsorbents upstream of liquefaction. The crystalline composition, make it a perfect solution to absorb the water and other impurities to obtain the pure liquid or gas as compared to other separation systems. Molecular sieves desiccants are widely effective in removing the water or moisture from different liquids and gases. Proper regeneration of molecular sieves in tsa processes. Molecular sieve adsorbents for natural gas processing.
This does not only involve choosing the right adsorbents, but also designing the adsorption and regeneration procedures so. As a result, the natural gas processing industry uses uops molsiv adsorbents for natural gas dehydration, mercury removal, co2 removal, natural gaslpg desulfurization and ammonia synthesis gas purification. Our team of engineers will design and commission a costefficient gas drying system using molecular sieves. Molecular sieve with a unique structure helps several systems to remove unwanted gas or liquid impurities to great extent. Natural gas dehydration with molecular sieve interra global. Mol sieve dehydration is a process where water vapors are removed from the gas streams using the highly effective desiccant material known as molecular sieves. This work focuses on the study of a pressure swing adsorption psa process for biogas upgrading using a carbon molecular sieve adsorbent.
Mokhatab, gas processing consultant, halifax, nova scotia, canada. In order to achieve such speci cations, the raw gas must pass through a series of puri cation steps, which compose the socalled natural gas chain. The 3a molecular sieve can remove moisture in both liquid and gas applications. When a molecular sieve unit is used for dehydration, it is possible to send the regeneration gas back to the feed after compression is performed to negate the pressure drop.
Ishimbaysky specialized chemical plant catalysts and sterlitamak plant catalysts. To validate the prediction of multicomponent adsorption at different concentrations, breakthrough curve experiments were. To regenerate the molecular sieve, several steps are generally involved. The combination of 2 to 3 beds, a heater, a condenser, and a dust filter work together to dry natural gas. Formation of the water phase will control the water content in the gas phase. Thermal regeneration is a widely used method in the oil and gas industry. Optimal design and operation of molecular sieve gas dehydration. Molecular sieves technical information bulletin sigma. Zeochem z306 zeochem z306 molecular sieve is a specially developed form of the 3a type crystal and it is a high value zeolite recommended for dehydration of hydrocarbon gas and liquid streams molecular sieves superior performance products for natural gas dehydration. At the end of regeneration, the molecular sieve can recover most of its original adsorption capacityi.
Zeolites molecular sieves, sorbents and catalysts for oil refining. Another key variable in the selection of a molecular sieve product, and the principal focus of this paper, is the binder used to hold the zeolite crystals together. Molecular sieves are crystalline metal aluminosilicates having a threedimensional interconnecting network of silica and alumina tetrahedra. Union carbide scientists invented molecular sieves over 60 years ago, and today uop scientists continue in their footsteps, creating new and better sieves for a wide variety of gas processing applications. Molsievebased dehydration technology desiccant dehydration dolphin onshore gas plant project molecular sieve package 3d drawing dumbarton field development molecular sieve package replicantes frames gas treatment dr. Adsorption equilibrium and diffusion data of pure components were used to predict the multicomponent behavior. Natural gas is commercially dehydrated in one of three ways 1 ab ti. Type 3a is used in the production of insulated glass, refrigerant drying, general moisture removal and the drying of natural gas, hydrocarbon liquids, ethanol and reactive monomers such as olefins. Failure analysis and faults diagnosis of molecular sieve. Natural gas dehydration by desiccant materials sciencedirect. Natural gas dehydration desiccants molecular sieves adsorption. This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was to build up a pilot scale unit for a natural gas.
Specifically, they discussed the benefits of standby time in the adsorption dehydration processes and impact of feed gas conditions. Practical considerations for the design of adsorbent beds. Optimal design and operation of molecular sieve gas dehydration unitspart 1. Modelling of natural gas sweetening and dehydration processes. Gases to be dehydrated cover straight natural gas, through heavier associated gases, and sour gases of.
In march 2004 the molecular sieve unit at the aventine renewable energy plant was brought on stream. Pdf natural gas dehydration by desiccant materials researchgate. Molecular sieve technology is widely used for the simultaneous removal of water and mercaptans from both gas and liquid feed streams. Molecular sieve for natural gas dehydration hengye. Water saturation of natural gas feeds for temperature swing adsorption in molecular sieve unit ng feeds to the dehydration unit consists of h 2 oco 2 ch 4 streams previously saturated with water in the process flow diagram pfd shown in fig. Natural gas dehydration by desiccant materials core. The experimental setup consists of cylinder filled with 3a molecular sieve to form a fixed bed, then pass through this bed natural gas with different water vapor. Methods for regeneration of molecular sieves include pressure change as in oxygen concentrators, heating and purging with a carrier gas as when used in ethanol dehydration, or heating under high vacuum. A reliable molecular sieve system is of paramount importance for any lng. The combination of an open crystal structure and a high.
The molecular sieve dehydration natural gas technique is considered to be one of the most important ones for the sweetening process of natural gas because these molecular sieves are desiccant and also have adsorption levels which can be used for drying the natural gas in a very efficient manner. Deep dehydration and desiccation for natural gas by using molecular sieve is the method featuring the widest application and the most mature technique. Wet natural gas rst enters the mol sieve section, passes through the inlet gas separator to remove any free liquids and then onto the inlet gas ltercoalescer to remove contaminants. Molecular sieves molecular sieve adsorbents zeochem. Additionally, molecular sieves can be usedto simultaneously remove sulfurous contaminants and dry the natural gas in preparation for further processing. Another strategy to dealing with disturbances is the placing controllers in manual. Pressure swing adsorption for biogas upgrading with carbon. Optimal design and operation of molecular sieve gas. Purification if the content does not meet the national standard, the sour natural gas must be subjected to purification and sulfur removal processes for normal use. Regeneration gas taken downstream of the dry gas filters is heated to. Glycol dehydration cannot get to these low water levels mole sieves used for this.
206 1505 1039 142 1246 586 58 823 745 1437 7 1260 1054 1440 779 189 910 913 1322 1048 1639 98 101 512 1333 1097 1587 423 796 671 1333 494 359 724 5 823 1426 314 210 1471 1445 111 607 1376 1188 1354